Triheterometallic Lanthanide Complexes Prepared from Kinetically Inert Lanthanide Building Blocks
نویسندگان
چکیده
منابع مشابه
Construction of polyoxometalates from dynamic lacunary polyoxotungstate building blocks and lanthanide linkers.
A series of polynuclear metal-oxo clusters have been constructed from the dynamic polyoxometalate (POM) building block {B-α-Sb(III)W9O33} and lanthanide (Ln) linkers via a stepwise synthetic strategy with the molecular formulas of [Ln2(H2O)4{WO2(pic)}2(SbW8O30)2](10-) (Na4Li6[La-1]·28H2O, Na3Li7[Pr-2]·30H2O) and [{Ln(H2O)}{Ln(pic)}(Sb3O4)(SbW8O31)(SbW10O35)]2(24-) (K2Na6Li16[Tb-3]·63H2O, Na9Li1...
متن کاملLanthanide Complexes for Luminescence Imaging Applications
In this article, imaging applications of luminescent complexes and recent advances in the design and photophysical behaviour of near-IR responsive complexes are reviewed. Various properties of the luminescent lanthanide complexes are also discussed in detail.
متن کاملLanthanide(III) Complexes of Oxamic Acid
The preparation, for the first time, of the deprotonated complexes of oxamic acid with Ce(III), Pr(III), Nd(III), Sm(III), Eu(III), Dy(III), Ho(III ) and Yb(III ) is reported. Properties, analytical results, conductometric measurements, magnetic moments and spectral data (IR and diffuse reflectance spectra) are discussed in terms of possible structural types and the nature of the bonding. Oxami...
متن کاملComplexes of triphenylphosphine oxide with lanthanide bromides
The reaction between hydrated lanthanide bromides and triphenylphosphine oxide in 1:3 and 1:4 ratios in ethanol gave a series of complexes [LnBr2(Ph3PO)4]Br (Ln = Pr, Nd, Gd, Tb, Er, Yb, Lu) which contain ethanol and water in the lattice, regardless of the ratio of reactants used. The single crystal x-ray structures of [NdBr2(Ph3PO)4]Br, [GdBr2(Ph3PO)4]Br and [YbBr2(Ph3PO)4]Br have been determi...
متن کاملCalibration beads containing luminescent lanthanide ion complexes.
The reliability of lanthanide luminescence measurements, by both flow cytometry and digital microscopy, would be enhanced by the availability of narrowband emitting, UV excited lanthanide calibration beads. 0.5-, 3-, and 5-microm beads containing a luminescent europium-complex are manufactured. The luminescence distribution of the 5-microm beads is measured with a time-delayed light-scatter-gat...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2017
ISSN: 1434-1948
DOI: 10.1002/ejic.201700027